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Nitrile (NBR)

NBR (nitrile, Buna N) is the standard oil-resistant rubber. It is the default for seals and gaskets that see petroleum oils and fuels, it is the least expensive good oil resistance available, and it is why most sealing hardware in the world is nitrile. What it will not do is sit outdoors or run hot.

PropertyValue
Temperature range-40 °C to +120 °C
Hardness40–90 Shore A
ACN content18–50 percent, and it decides everything below
Contains fluorineNo

ACN content is the spec that matters

Nitrile is a copolymer of butadiene and acrylonitrile, and the acrylonitrile fraction, the ACN content, is the number that sets how the compound behaves. ACN is not a quality grade. It is a trade-off you pick, and picking it wrong is the most common reason a nitrile part disappoints.

ACN contentWhat you gainWhat you give up
Low, around 18–28 percentCold flexibility, a seal that still works well below -40 °COil resistance, more swell in fuel and aromatic oils
Medium, around 33 percentThe general-purpose balance most nitrile parts useNothing in particular, and nothing exceptional either
High, around 40–50 percentMaximum resistance to fuel and aromatic oils, minimum swellLow-temperature performance, brittleness in the cold

You cannot have both ends. A high-ACN compound that shrugs off gasoline will stiffen and leak on a cold morning, and a low-ACN compound that stays flexible at -45 °C will swell in the same fuel. When we quote a nitrile part, the service temperature floor and the media together pick the ACN. That is why we ask about both.

Where nitrile fails

Ozone cracking is the usual one. Nitrile has unsaturated double bonds in its backbone, and atmospheric ozone attacks them, so a part under tension outdoors develops fine surface cracks perpendicular to the strain and then splits. This is not heat and it is not the fluid. It is the air. Antiozonants in the compound delay it, they do not remove it, so a nitrile part that will live outdoors under stress is the wrong specification rather than a compounding problem.

The other limit is heat. Nitrile is comfortable to about 100 °C continuous and can be pushed to 120 °C, above which it hardens, loses elongation, and takes permanent set. If your part is running at 130 °C in oil, nitrile is not the answer and HNBR usually is, at a fraction of the cost of going to FKM.

Typical uses

  • O-rings, rod seals, and shaft seals in hydraulic and pneumatic systems
  • Fuel-system components, hoses, and gaskets
  • Flat and profiled gaskets in oil-wetted joints
  • Dynamic seals where abrasion and tear resistance matter, an area where nitrile beats FKM

What we do with it here

Nitrile is one of the families we mix ourselves, so ACN content, filler loading, and cure system are formulation choices we make against your application rather than a catalog number we order in. Compounds are verified in our ISO/IEC 17025:2017 accredited lab before they are molded, and finished parts are tested in the same building.

Viton vs Buna