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Fluoroelastomer (FKM)

FKM, usually called by the Viton™ trade name, is the premium high-performance elastomer for heat, fuels, and aggressive chemicals. It is the broadest chemical envelope in general industrial use and it has the lowest compression set of anything you are likely to specify. It is also expensive, poor in the cold, and it contains fluorine, which is now a program-level question rather than a chemistry footnote.

PropertyValue
Temperature range-20 °C to +205 °C, with excursions higher
Hardness55–90 Shore A
Compression setThe best available in general industrial use
Contains fluorineYes, and it falls inside the PFAS restrictions in progress

Grade decides the envelope

FKM is not one material. The grades differ in fluorine content and in the monomers used, and that changes both what the part resists and how cold it can go. Specifying FKM without specifying which kind is how a part ends up technically correct and functionally wrong.

TypeRoughlyWhere it earns its place
A66 percent fluorine, the copolymerThe general-purpose grade, best low-temperature flexibility of the family, standard oils and fuels
B68–69 percent fluorine, the terpolymerBetter fluid resistance than A, the usual choice for aggressive chemical service
F70 percent fluorineMaximum resistance to oxygenated fuels and methanol blends, at the cost of cold performance
GLT and similarLow-temperature gradesService down toward -40 °C where standard FKM would already be glass-hard

The pattern is consistent: more fluorine buys chemical resistance and costs you low-temperature flexibility. A standard FKM part is effectively rigid below about -20 °C, so a seal that has to survive a cold start needs a low-temperature grade specified deliberately.

Where FKM fails

Three environments defeat it and they surprise people, because FKM is otherwise so capable. Hot water and steam attack it. Amines, including the amine inhibitors in many coolants and process fluids, attack it. Ketones and esters, brake fluid among them, swell it badly. The field failure we see most is an FKM seal specified on temperature alone, dropped into a steam or amine-inhibited system, and gone in weeks. That duty belongs to AFLAS or EPDM depending on the rest of the picture.

Mechanically it is also less tough than nitrile, with lower tear and abrasion resistance, so a dynamic seal taking rough installation or particulate wear is not automatically better in FKM.

The fluorine question

FKM contains fluorine and sits inside the scope of the PFAS restrictions moving through the EU and several US states. For most parts today that changes nothing. For programs that have committed to removing fluorine from the assembly, it decides the material before performance is discussed, and the work becomes finding how much of the FKM envelope you actually use.

Typical uses

  • High-temperature static seals, above where nitrile and HNBR stop
  • Fuel-system components, including oxygenated and blended fuels with the right grade
  • Aerospace and chemical-process seals
  • Anywhere long-term compression set under heat is the controlling requirement

HNBR vs FKM