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Acrylic (Polyacrylate, ACM)

Polyacrylate exists for one job: hot oil. It holds up in engine and transmission fluid at temperatures where nitrile has already hardened and cracked, and it does so at a fraction of the cost of a fluoroelastomer. It is also poor in the cold and it does not tolerate water.

PropertyValue
Temperature range-20 °C to +150 °C
Hardness50–90 Shore A
Best atHot petroleum oil, heat aging, ozone
Contains fluorineNo

The gap between nitrile and FKM

Nitrile is the default oil rubber and it runs out of heat resistance around 100 to 120 °C in continuous service. FKM handles 200 °C and costs several times more. Between those sits a large population of automotive and industrial parts running at 130 to 150 °C in oil, and ACM is the family built for that band. Specifying FKM for those parts works and overpays; specifying nitrile fails in the field.

It also resists ozone and heat aging well, so a part in an engine bay is not fighting the environment outside the oil either.

How we compound and test it

ACM uses cure systems that are more sensitive than a standard sulfur cure and typically needs a post-cure to develop full properties and to drive off residuals. Skipping or shortening the post-cure produces a part that passes a dimensional check and then shows high compression set in service, which is the failure that looks like a design problem and is actually a process one.

We run compression set at the service temperature rather than at a standard 100 °C, because for this family the whole point is behaviour at the top of the range.

The two mistakes buyers make

The first is water. ACM hydrolyses. Coolant, steam, or a wash-down environment will break it down, and a seal that sees both oil and water is not an ACM part regardless of the temperature.

The second is cold. At -20 °C it is already stiff, and below that it is effectively rigid. A vehicle part that has to seal on a cold start in a northern winter needs a different family or a modified grade, and that has to be established before tooling.

Typical uses

  • Transmission and engine oil seals
  • Shaft seals in hot petroleum oil
  • O-rings and gaskets in the 130–150 °C oil band
  • Automotive parts where FKM is over-specified
  • Hot oil service away from water and coolant